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- The zeroth law of thermodynamics, which underlies the definition of temperature.
- The first law of thermodynamics, which mandates conservation of energy, and states in particular that heat is a form of energy.
- The second law of thermodynamics, which states that the entropy of an isolated macroscopic system never decreases, or (equivalently) that perpetual motion machines are impossible.
- The third law of thermodynamics, which concerns the entropy of a perfect crystal at absolute zero temperature, and implies that it is impossible to cool a system all the way to exactly absolute zero.
Thermodynamics is the study of conversion of energy between different forms such as heat and work. This kind of conversion takes place due to changes in states of temperature, volume, and pressure of gaseous mediums like steam and air. The entire field of thermodynamics relies heavily on three basic laws called laws of thermodynamics. These laws of thermodynamics are given below.
First law of thermodynamics
The change in energy of a closed thermodynamic system is equal to amount of heat energy supplied to or removed from the system and, and the work done on or by the system
Second law of thermodynamics
The total entropy of any isolated thermodynamic system always increases over time approaching maximum value.
Third law of thermodynamics
As a system asymptotically approaches absolute zero of temperature, all processes virtually cease and the entropy of the system asymptotically approaches a minimum value.
Thermodynamics: Chapter of the physics where phenomena which are ranging in temperature, have the primary role of the study. These phenomena involve the thermal motion of matter and energy transformation from one form to another.
Thermodynamics is based on experiences from where came out laws or principles of law, known as zero law, the first (first principle), the second law (second principle) and the third law(third principle).Zero law of thermodynamics
Two thermodynamic systems put in contact and isolated from environment, reach themselves (eventually) the state of thermal equilibrium.
Zero law is the basis for methods of measurement of body temperature. First principle of thermodynamics
This principle is an extension of the law of energy conservation in the processes occurring thermal motion of matter.
The existence of heat as a form of energy transfer has been a particular problem in the history of thermodynamics. Only Joule's experiments proved and confirmed the similar nature of heat and mechanical work. Subsequent experiments showed that mechanical work and heat are the only forms of energy transfer between a thermodynamic system and environment. The first principle of thermodynamics introduces a new size of a state called internal energy, which is equal to the sum of all the kinetic energy of molecules of a body. Thus, the first principle (Mayer formulation ) says that a system adiabatically isolated from the environment can change his internal energy due to external mechanical work performed (ΔL = ΔQ = U2-U1). If the system is adiabatically isolated and there is heat exchange between system and environment,then ΔU = ΔQ-ΔL. To conclude, the first law of thermodynamics is the law of conservation of matter and existing energy. The first law of thermodynamics has a great importance in the study of thermal machines. Thermal machine is called that device which takes heat from the outside making it into mechanical work. The second principle of thermodynamics Conservation laws are expressed mathematically in terms of the equalities. So, the first principle allows the transformation of energy from one form to another, as long as the total energy are preserved, therefore there is no restriction on converting heat into mechanical energy and vice versa. From mathematical point of view, principle II is represented by an inequality and is not a conservation law. Formulation of the second principle, that is most important in our study, is the formulation that includes a new size of state characterizing the organization of a system, called entropy. Increasing entropy principle says:
In any adiabatic process, the entropy of any system increases or remain constant, ΔS ≥ 0, where "=" is for reversible processes and ">" for irreversible processes. This principle is important precisely because it says that in nature there is a law of change whose directions are downward and not upward as evolution implies. Classical thermodynamic says entropy increases for any physical process and the energy tends to lower levels of use.
Statistical thermodynamics says that every amount of energy has an associated size of the state called entropy which measures the degree of disorder of the system.
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