Is the relationship possible to happen?
There are several relationships woven together in Kiss of the Spider Woman. It is possible for each of them to happen, but not likely for all of them to happen at once. In that way, the whole novel is like one of Molina's tales.
To expand on that a little bit, it is very possible for...
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Yes, the two homosexual prisoners, Molina and Valentin, both whom were opposite in thousands of ways, forged a close and intimate bond in their cell, and their sex relationship to each other improved as they progressed ahead, blossoming into true love, where they need each other to survive in the Nazi regime.