Quote at least one line that directly associates Chillingworth with the devil. Cite the page number.This is in Chapter 14.

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favoritethings eNotes educator| Certified Educator

In Chapter XIV, a chapter in which Chillingworth and his wife, Hester Prynne, discuss the Reverend Dimmesdale, Hester's punishment, and Chillingworth's machinations, the narrator says, "In a word, old Roger Chillingworth was a striking evidence of man’s faculty of transforming himself into a devil, if he will only, for a reasonable space of time, undertake a devil’s office."  Hester is somewhat shocked by the sight of her husband because he looks so different from the way he used to.  His nature seems to have been completely corrupted by his attempts to torture Arthur Dimmesdale, the man with whom Hester sinned.  He has become a devil after acting like one for so long.

About Dimmesdale, and Chillingworth's torture of him, Hester says, 
"'Better he had died at once!' [...] 'Yea, woman, thou sayest truly!' cried old Roger Chillingworth, letting the lurid fire of his heart blaze out before her eyes."  This "lurid fire" seems to refer to the fires of hell which have been kindled in his heart since he began to exact his evil vengeance on Dimmesdale.
 
Finally, Chillingworth says, "'I pity thee, for the good that has been wasted in thy nature.'  'And I thee,' answered Hester Prynne, 'for the hatred that has transformed a wise and just man to a fiend!'"  The devil is often referred to as the "Arch Fiend," and so this quotation may be interpreted as Hester again comparing Chillingworth to the devil.
dymatsuoka eNotes educator| Certified Educator

In the sixth and seventh paragraphs of Chapter 14 - (page numbers vary greatly from edition to edition of the book) - Chillingsworth is described thus:

"...there came a glare of red light out of his eyes; as if the old man's soul were on fire, and kept on smoldering duskily within his breast, until, by some casual puff of passion, it was blown into a momentary flame...Chillingsworth was a striking evidence of man's faculty of transforming himself into a devil, if he will only, for a reasonable space of time, undertake a devil's office".

Chillingsworth's evil obsession with revenge for the past seven years has changed him from the "intellectual and studious man, calm and quiet" whom Hester remembers, into something akin to a fiend. Chillingsworth also is aware of his own transformation, and considers it beyond his power to stop it.

sullymonster eNotes educator| Certified Educator

Pearl, insightful young girl that she is, warns her mother away from Chillingworth in Paragraph 23 of Chapter 10.  She tells her mother Chillingworth is "the black man" which is another word for devil:

Hester Prynne, likewise, had involuntarily looked up, and all these four persons, old and young, regarded one another in silence, till the child laughed aloud, and shouted--"Come away, mother! Come away, or yonder old black man will catch you! He hath got hold of the minister already. Come away, mother or he will catch you! But he cannot catch little Pearl!"

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The Scarlet Letter

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