In my opinion, Holden's sister Phoebe is the least phony character in this book.
The reason that I say that is that she does not seem to be trying to pretend to be something that she is not. She seems to have genuine emotions and to act based on those emotions.
I think that this is probably because she is the youngest character in the book -- the only one who is not sexually mature. I think that the book is sort of saying that sex is a lot of what makes people phony.
That brings me to my other choice for characters who aren't phony -- the nuns. But I figure that they are not enough of character to count.
Anyway, Phoebe lets people know what she's thinking. She loves Holden, but when she's mad at him she won't let him touch her, for example.