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Why does 5d1 fill before 4f in lanthanum z=57?
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- Aufbau principle states that filling of orbitals should take place by starting from lowest energy level.
- Pauli exclusion principle states that no two electron in a orbital will have same quantum numbers.
- Hund's rule states that all sub orbitals in a orbitals are first filled with one electron and then pairing of electron takes place.
We have to follow three principles while writing electronic configuration:
1) Aufbau principle,
2) Pauli exclusion principle,
3) Hund's rule
Electronic configuration = `[Xe]5d^1 6s^2`
This is the exception which do not follow the rule.
The expected configuration is [Xe]6s^2 4f^1
The 4f sub shell and 5d sub shell has almost same energy level so it is tought to tell the diference.
Lanthanides has a special feature known as Lanthanide contraction.
This Lanthanide contraction explains why 5s and 5p orbitals Penetrate the 4f sub-shell and filling of electron takes place in 5d sub shells instead of in 4f subshell.
Posted by sanjeetmanna on August 13, 2012 at 7:23 PM (Answer #1)
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