During the 1800-1900 time period?
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Czar Alexander II freed most of Russia's serfs in 1861:
( http://michael-streich.suite101.com/emancipation-of-the-serfs-by-alexander-ii-a95378 ).
However, the real changes in Russian society, economics, and politics didn't take place until just after your time period, during the Russian Revolution in 1917.
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