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I don't quite understand this part in the explanation below "molecular dipole are only...
I don't quite understand this part in the explanation below "molecular dipole are only a fraction of the size of the charges on an ion"
How Polar Bonds create Inter-molecular Forces:
The charges on each end of a molecular dipole are only a fraction of the size of the charges on an ion, but they do cause electrical forces to occure between nearby molecules.
Can you please give an easier explanation?
1 Answer | add yours
Think of this in terms of magnitude or size. A true ion is something like the sodium cation (Na+) or the chloride anion (Cl-). There is a full charge on the ion that is a whole integer value (1, 2, 3, etc.). A molecular dipole is not a full charge on an atom like you find in an ion. A dipole is a partial charge. If two atoms covalently bonded together experience a dipole, that means that one of the atoms will have a partial positive charge and the other atom will have a partial negative charge. This is because the electron density in the bond is shifted toward the the more electronegative atom. But the important point here is that a dipole is merely a partial charge, whereas an ion is a full charge. This is why they use the phrase "molecular dipole are only a fraction of the size of the charges on an ion."
Posted by ncchemist on July 2, 2013 at 3:05 AM (Answer #1)
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