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An unknown gas shows a density of 2.4g/litre at 273 degree celcius and 140 mm Hg...

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jennifer881997 | Student, Grade 11 | eNoter

Posted June 11, 2012 at 11:15 AM via web

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An unknown gas shows a density of 2.4g/litre at 273 degree celcius and 140 mm Hg pressure.What is the gram molecular mass of this gas?

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zopalwie | Student , Grade 10 | Honors

Posted June 11, 2012 at 1:05 PM (Answer #1)

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PV = nRT
n = mass / mw

substituting
PV = (mass / mw) RT

rearrainging
mw = (mass / V) RT / P = ρ RT/P

mw = molecular weight, molar mass, etc
ρ = density = mass / V = 2.4 g/L
R = ideal gas constant = 0.08206 Latm/moleK
T = 273C = 273+273 K = 546 K
P = 140 mm Hg = 140 mm Hg x (1 atm / 760 mm Hg) = 0.184 atm

substituting...
mw = (2.4 g/L) x (0.08206 Latm/moleK) x (546 K) / (0.184 atm) = 584.41 g/mole

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sanjeetmanna | College Teacher | (Level 3) Assistant Educator

Posted August 22, 2012 at 2:34 AM (Answer #2)

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Given

density = 2.4 g/L

Mass = 2.4 g

Volume = 1 Litre

Pressure = 140 mmHg = 0.184 atm

absolute temperature = 273 C + 273 = 546 K

Gas constant = 0.082 `LatmK^-1mol^-1`

molar mass = ?

Formula

`PV = nRT`

`n = (PV)/(RT)`

`n = (0.184*1)/(0.082*546)`

n = 0.00410

n = moles = `(mass)/(molar mass)`

molar mass = mass/moles

Molar mass = `(2.4)/(0.00410)`

Molar mass = 585.3 g/mol

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